Analytical methods for Challenge14 Sample: The compound is a natural product. The molecular formula of the precursor [M+H]+ is C21H25N2O3. Precursor ion type: [M+H]+ Molecular formula of precursor ion: C21H25N2O3 Instrument: LCMS-IT-TOF (Shimadzu) Ion source: APCI, positive ion mode Sample Introduction: Infusion of water solution CID condition: Gas 35%, CID energy 40%